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Creators/Authors contains: "Bartholome, Tyler A"

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  1. ; ; ; ; ; (, Chemical Communications)
    Phenanthrylboroles with 3,4-conjugation have been synthesized which react with azides to furnish B,N-pyrene analogues. 
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  2. ; ; ; (, Dalton Transactions)
    A series of anionic group 6 tricarbonyl and neutral rhodium dicarbonyl complexes featuring a boratabenzene (L1, with a phenyl on boron, a trimethylsilyl group on the adjacent carbon and methyl groups on the other carbons) and a borataphenanthrene ligand (L2, with a phenyl group on boron and a trimethylsilyl group on the adjacent carbon) are prepared. The donor ability of the boracyclic ligands is evaluated experimentally and theoretically by the stretching frequencies of the CO ancillary ligands. Overall, the donor ability of the ligands falls into the following trend: L1 > cyclopentadienyl > L2 > mesitylene. 
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  3. ; ; ; ; ; ; (, ACS Catalysis)
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  4. ; ; ; ; ; ; ; ; (, Inorganic Chemistry)
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  5. ; ; ; ; ; (, Organometallics)
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  6. ; ; ; ; ; ; (, Chemical Reviews)
    null (Ed.)
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  7. ; ; (, Dalton Transactions)
    The reactions of 9-phenyl-9-borafluorene with trimethylsilyldiazomethane in a 1 : 1 and 1 : 2 stoichiometry furnished the corresponding BC 5 and BC 6 heterocycles via the formal insertion of one and two carbene units. 
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  8. ; ; ; ; (, Angewandte Chemie International Edition)
    Abstract The 9‐borataphenanthrene anion is easily accessed by deprotonation of a 9,10‐dihydro‐9‐boraphenanthrene and its diverse reactivity is investigated. Alkylation occurs at the carbon atom adjacent to boron, and room temperature hydroboration occurs across the B=C bond. The π‐manifold of the central BC5ring coordinates to chromium in an η6fashion while only the B=C unit binds η2to gold, indicating versatility of the 9‐borataphenanthrene anion as a ligand. Supporting calculations rationalize the reactivity and aromaticity is corroborated by nucleus‐independent chemical shift (NICS) indices. 
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